锂(药物)
电解质
歧化
超氧化物
纳米线
氧气
无机化学
吸附
材料科学
阴极
化学
化学工程
纳米技术
电极
催化作用
有机化学
内分泌学
物理化学
工程类
医学
酶
作者
Gwang‐Hee Lee,Myeong-Chang Sung,Yoon Seon Kim,Bobae Ju,Dong‐Wan Kim
出处
期刊:ACS Nano
[American Chemical Society]
日期:2020-11-11
卷期号:14 (11): 15894-15903
被引量:9
标识
DOI:10.1021/acsnano.0c07262
摘要
We report a technique for effectively neutralizing the generation of harmful superoxide species, the source of parasitic reactions, in lithium–oxygen batteries to generate stable substances. In organic electrolytes, organogermanium (Propa-germanium, Ge-132) nanowires can suppress solvated superoxide and induce strong surface-adsorption reaction due to their high anti-superoxide disproportionation activity. Resultantly, the effect of organogermanium nanowires mitigate toxic oxidative stress to stabilize organic electrolytes and promote good Li2O2 growth. These factors led to long duration of the electrolytes and impressive rechargeability of lithium–oxygen batteries.
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