In‐Synthesis Se‐Stabilization Enables Defect and Doping Engineering of HgTe Colloidal Quantum Dots

Abstract Colloidal Quantum Dots (CQDs) of mercury telluride (HgTe) hold particular appeal for infrared photodetection due to their widely tunable infrared absorption and good compatibility with silicon electronics. While advances in surface chemistry have led to improved CQD solids, the chemical stability of HgTe material is not fully emphasized. In this study, it is aimed to address this issue and identifies a Se‐stabilization strategy based on the surface coating of Se on HgTe CQDs via engineering in the precursor reactivity. The presence of Se‐coating enables HgTe CQDs with improved colloidal stability, passivation, and enhanced degree of freedom in doping tuning. This enables the construction of optimized p‐i‐n HgTe CQD infrared photodetectors with an ultra‐low dark current 3.26 × 10 −6 A cm⁻ 2 at −0.4 V and room‐temperature specific detectivity of 5.17 × 10 11 Jones at wavelength ≈2 um, approximately one order of magnitude improvement compared to that of the control device. The stabilizing effect of Se is well preserved in the thin film state, contributing to much improved device stability. The in‐synthesis Se‐stabilization strategy highlights the importance of the chemical stability of materials for the construction of semiconductor‐grade CQD solids and may have important implications for other high‐performance CQD optoelectronic devices.