A Nitro‐Modified Luminescent Hydrogen‐Bonded Organic Framework for Non‐Contact and High‐Contrast Sensing of Aromatic Amines

The global demand for intelligent sensing of aromatic amines has consistently increased due to concerns about health and the environment. Efforts to improve material design and understand mechanisms have been made, but highly efficient non-contact sensing with host-guest structures remains a challenge. Herein, we report the first example of non-contact, high-contrast sensing of aromatic amines in a hydrogen-bonded organic framework (HOF) based on a nitro-modified stereo building block. Direct observation of binding interactions of trapped amines is achieved, leading to charge separation-induced emission quenching between host and guests. Non-contact sensing of aniline and diphenylamine is realized with quenching efficiencies up to 91.7 % and 97.0 %, which shows potential for versatile applications. This work provides an inspiring avenue to engineer multifunctional HOFs via co-crystal preparations, thus enriching applications of porous materials with explicit mechanisms.