合成气
阳极
甲烷
固体氧化物燃料电池
材料科学
氢
气体成分
传热
多物理
温度梯度
热力学
化学工程
化学
电极
有限元法
物理化学
有机化学
工程类
物理
量子力学
作者
Weiqiang Cai,Jinliang Yuan,Qingrong Zheng,Wanneng Yu,Zibin Yin,Zhonggang Zhang,Yuyao Pei,Shian Li
出处
期刊:Crystals
[MDPI AG]
日期:2022-11-23
卷期号:12 (12): 1697-1697
标识
DOI:10.3390/cryst12121697
摘要
To elucidate the thermofluid reacting environment and thermal stress inside a solid oxide fuel cell (SOFC), a three-dimensional SOFC model is implemented by using the finite element method in the commercial software COMSOL Multiphysics®, which contains both a geometric model of the full-cell structure and a mathematical model. The mathematical model describes heat and mass transfer, electrochemical reactions, internal reforming reactions, and mechanical behaviors that occur within the cell. A parameter study is performed focusing on the inlet fuel composition, where humidified hydrogen and methane syngas (the steam-to-carbon ratio is 3) as well as the local distribution of temperature, velocity, gas concentrations, and thermal stress are predicted and presented. The simulated results show that the fuel inlet composition has a significant effect on the temperature and gas concentration distributions. The high-temperature zone of the hydrogen-fueled SOFC is located at the central part of units 5, 6, and 7, and the maximum value is about 44 K higher than that of methane syngas-fueled SOFC. The methane-reforming and electrochemical reactions in the anode active layer result in a significant concentration gradient between the anode support layer and the active layer of the methane syngas-fueled SOFC. It is also found that the thermal stress distributions of different fuel inlet compositions are rather different. The maximum stress variation gradient between electrode layers of hydrogen SOFC is larger (44.2 MPa) than that of methanol syngas SOFC (14.1 MPa), but the remaining components have a more uniform stress distribution. In addition, the electrode layer of each fuel SOFC produces a significant stress gradient in the y-axis direction, and stress extremes appear in the corner regions where adjacent assembly components are in contact.
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