A new highly powered supercapacitor electrode of advantageously united ferrous tungstate and functionalized multiwalled carbon nanotubes

超级电容器 材料科学 纳米复合材料 热重分析 电容 电极 化学工程 碳纳米管 纳米技术 化学 工程类 物理化学
作者
Ponnaiah Sathish Kumar,P. Prakash,Srinivasan Alagar,Chelladurai Karuppiah
出处
期刊:Journal of Power Sources [Elsevier]
卷期号:482: 228892-228892 被引量:40
标识
DOI:10.1016/j.jpowsour.2020.228892
摘要

The disadvantages that prevent supercapacitors from swapping batteries in most of the applications are linear discharge voltage, low specific energy, and high cost. Here, we report the fabrication of a new nanocomposite electrode by strategically combining ferrous tungstate and functionalized multiwalled carbon nanotubes (FeO4W/f-MWCNTs) hydrothermally for high-performance supercapacitors. This supercapacitor electrode shows specific capacitance as high as 875 Fg−1. The cycle tests show capacitance retention of 89.17% after huge 10,000 cycles in three electrode system. Further, a symmetric supercapacitor device made of FeO4W/f-MWCNTs delivers a high specific capacitance with good capacitance retention. Such a discovery of a novel electrode certainly paves way for the development of advanced nanocomposite electrodes for energy storage applications with substantial improvement in charge time, specific power, cycle life, and safety. Analytical techniques such as ultraviolet–visible spectroscopy and Fourier transform infrared spectroscopy confirm the presence of functionalities in the composite, whereas thermogravimetric analysis of the nanocomposite reveal better thermal stability compared to its counterparts. The crystallinity of the composite is ascertained by X-ray diffraction technique. The interplanner spacing (dhkl) in the nanomaterial is measured from high-resolution transmission electron microscopy and selected area electron diffraction methods. Energy-dispersive X-ray analysis is used for elemental analysis.
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