Degradation of Acid Orange 7 by peroxymonosulfate activated with the recyclable nanocomposites of g-C3N4 modified magnetic carbon

化学 纳米复合材料 活性炭 橙色(颜色) 降级(电信) 核化学 环境化学 化学工程 吸附 有机化学 食品科学 计算机科学 电信 工程类
作者
Furong Guo,Jiahua Lu,Qing Liu,Ping Zhang,Aiqing Zhang,Yingjie Cai,Qiang Wang
出处
期刊:Chemosphere [Elsevier]
卷期号:205: 297-307 被引量:48
标识
DOI:10.1016/j.chemosphere.2018.04.139
摘要

Carbon-based catalysts have attracted high attention since they are greener and cheaper, while magnetic nanomaterials are very useful in environmental application because of the easy recovery and operation given by the magnetic separability. Therefore, graphitic carbon nitride modified magnetic carbon nanocomposites Fe3O4@C/g-C3N4 was prepared herein for the first time as a new carbon-based catalyst for the activation of peroxymonosulfate (PMS). The catalytic properties of Fe3O4@C/g-C3N4 in activating PMS for the degradation of Acid Orange 7 (AO 7), a model organic pollutant, were investigated. AO 7 degradation efficiency was significantly enhanced after modification of Fe3O4@C with g-C3N4, and the composite Fe3O4@C/g-C3N4 from loading of 5 wt% g-C3N4 and calcined at 300 °C for 30 min exhibited the best performance. AO 7 could be efficiently decolorized using the "Fe3O4@C/C3N4 (5%) + PSM" system within the pH range of 2-6, and 97% of AO 7 could be removed in 20 min without pH adjustment (pH = 4). Radical quenching and EPR studies confirmed that both sulfate and hydroxyl radicals produced from PMS activation were the active species responsible for the oxidation of AO 7. The degradation mechanism was suggested based on the experimental results and XPS analyses. It was proposed that the CO groups on the carbon surface of Fe3O4@C rather than the CO in g-C3N4 played a key role as the active sites for PMS activation. The catalyst was magnetically separable and displayed good stability and reusability, thus providing a potentially green catalyst for sustainable remediation of organic pollutants.
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