多硫化物
共价键
锂(药物)
硫黄
吸附
氧化还原
化学工程
阴极
混合材料
催化作用
纳米技术
材料科学
化学
无机化学
电极
有机化学
冶金
电解质
物理化学
内分泌学
工程类
医学
作者
Liping Si,Jianyi Wang,Zicong Lu,Zhida Chen,Lianjie Zhang,Hai‐Yang Liu
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2022-07-13
卷期号:5 (7): 8554-8562
被引量:5
标识
DOI:10.1021/acsaem.2c01091
摘要
Lithium–sulfur (Li-S) batteries with high energy density, environmental friendliness, and low cost have still suffered from the short cycle life due to the shuttle effect of the dissoluble polysulfide intermediates. In this work, a hybrid host comprising ceric dioxide (CeO2) and covalent organic frameworks (COFs) was developed for the sulfur cathode. The hybrid host of CeO2/COFs manifests strong interaction with the polysulfide. Moreover, the polar interface of CeO2 and the highly 2D ordered structure of COFs endow good electrochemically catalytic activity, which accelerates the redox reaction and restrains the shuttle effect. Owing to the chemical and physical adsorption surface, the hybrid host of CeO2/COFs demonstrates a high initial capacity (1384 mAh g–1) and low decay rate (0.1%) at 0.5C. Collectively, the in situ hybrid strategy has high potential in elevating the performance of Li-S batteries.
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