材料科学
光电流
铁酸锌
退火(玻璃)
纳米棒
结晶度
氧化锡
分解水
兴奋剂
微波食品加热
化学工程
尖晶石
光电子学
纳米技术
分析化学(期刊)
锌
冶金
复合材料
光催化
物理
工程类
催化作用
化学
量子力学
生物化学
色谱法
作者
Ju Hun Kim,Jin Hyun Kim,Ji‐Wook Jang,Jae Young Kim,Sun Hee Choi,Ganesan Magesh,Jinwoo Lee,Jae Sung Lee
标识
DOI:10.1002/aenm.201401933
摘要
1D zinc ferrite (ZnFe 2 O 4 ) photoanode is fabricated on an F‐doped tin oxide substrate at a low temperature by an all‐solution method. To activate the material for photoelectrochemical water splitting, the hybrid microwave annealing (HMA) is applied with graphite powder as a susceptor. Thus, HMA treatment of ZnFe 2 O 4 photoanode synthesized at 550 °C increases the photocurrent density of water oxidation by 15 times. In contrast, the conventional thermal annealing at 800 °C brings only 1.7‐fold increase. The various physical characterizations and hole scavenger photooxidation experiments with H 2 O 2 reveal that the post‐HMA treatment anneals the surface defect states and enhances the crystallinity. Hence, HMA treatment is effective to suppress charge‐carrier recombination both on the surface and in the bulk of ZnFe 2 O 4 to bring out its latent solar water‐splitting activity.
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