电解质
阳极
阴极
电池(电)
石墨
材料科学
电化学
化学工程
接口(物质)
电极
锂(药物)
无机化学
法拉第效率
锂电池
快离子导体
插层(化学)
化学
电气工程
复合材料
工程类
热力学
物理
物理化学
毛细管作用
功率(物理)
毛细管数
作者
Bin Li,Yaqiong Wang,Haibo Rong,Yating Wang,Jiansheng Liu,Lidan Xing,Mengqing Xu,Weishan Li
出处
期刊:Journal of materials chemistry. A, Materials for energy and sustainability
[The Royal Society of Chemistry]
日期:2013-01-01
卷期号:1 (41): 12954-12954
被引量:131
摘要
To improve the cyclability of a LiMn2O4/graphite lithium ion battery at elevated temperature, a carbonate-based electrolyte using prop-1-ene-1,3-sultone (PES) as additive was developed. The cycling performance of the LiMn2O4/graphite cell, based on the developed electrolyte at 60 °C, was evaluated by a constant current charge/discharge test, with comparison of the electrolyte using vinylene carbonate (VC) as additive. It was found that the cell based on the developed electrolyte exhibits better cyclability and exhibits better dimensional stability at elevated temperatures. The capacity retention is 91% and the swell value in thickness is 3.4% for the cell with PES after 150 cycles at 60 °C, while the respective values were 68% and 36.4% for the cell without additive, and 82% and 9.1% for the cell with VC. The results obtained from scanning electron spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, thermal gravimetric analysis, and molecular energy level calculations show that PES favors the formation of a stable solid electrolyte interphase, not only on the anode but also on the cathode of the LiMn2O4/graphite battery, effectively preventing electrolyte decomposition.
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