光催化
异质结
光致发光
可见光谱
钙钛矿(结构)
扫描电子显微镜
化学
光谱学
透射电子显微镜
傅里叶变换红外光谱
漫反射红外傅里叶变换
光化学
材料科学
化学工程
光电子学
催化作用
纳米技术
结晶学
有机化学
工程类
物理
量子力学
复合材料
作者
Mahdieh Ghobadifard,Gelareh Feizi,Sajjad Mohebbi
摘要
The CeCoO 3 /MoS 2 heterojunction was successfully prepared through the hydrothermal method. The synthesized heterojunction structure was characterized by various techniques and applied to the conversion of methylene blue (MB) under irradiation of visible light. To characterize the new heterojunction structure, Fourier transformed infrared (FT‐IR), field emission scanning electron microscope (FE‐SEM), energy‐dispersive X‐ray spectroscopy (EDXS), X‐ray diffraction (XRD), photoluminescence spectroscopy (PL), differential reflectance spectroscopy (DRS), and transmission electron microscopy (TEM) analyses were used. The FE‐SEM images illustrated the successful deposition of MoS 2 flower‐like on the surface of CeCoO 3 perovskite with 46 nm as an average size. The influence of the amount of catalyst, temperature, pH, and electron acceptor were investigated. By CeCoO 3 /MoS 2 heterostructures photocatalyst, the conversion rate of MB reached 98% within 20 min, whereas by CeCoO 3 perovskite no significant conversion was observed in MB. The higher photocatalytic performance of CeCoO 3 /MoS 2 heterostructures is assigned to their lower charge recombination compared to CeCoO 3 perovskite. Moreover, the photocatalytic mechanism and recycling experiments of CeCoO 3 /MoS 2 heterostructures are discussed in detail. The CeCoO 3 /MoS 2 heterostructures are thus promising photocatalysts for the cleanup of polluted water.
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