Pore structure evolution of tar-rich coal with temperature-pressure controlled simulation experiments

大孔隙 tar(计算) 压实 地质学 化学工程 煤焦油 介孔材料 多孔性 矿物学 材料科学 化学 岩土工程 有机化学 催化作用 程序设计语言 工程类 计算机科学
作者
Shuai Shi,Jinxian He,Xiaoli Zhang,Ziqi Yu,Jian Wang,Tiantian Yang,Wei Wang
出处
期刊:Fuel [Elsevier BV]
卷期号:354: 129298-129298 被引量:17
标识
DOI:10.1016/j.fuel.2023.129298
摘要

Tar-rich coal, with a tar yield of 7–12%, has significant potential for hydrocarbon resources. In this study, typical tar-rich coal samples from Daliuta mining area were selected as the research object to conduct temperature–pressure controlled simulation experiments that simulated stratigraphic conditions. The pore characteristics of the tar-rich coal during coal metamorphism were studied, and the pore evolution law of the tar-rich coal was revealed. The findings demonstrate that this experiment successfully simulates all coal ranks, from low coal rank to high coal rank. Tar-rich coals contain pores of five different genetic types. Gas pores and fissures exhibit a tendency toward growth, while cellular pores are gradually broken and collapsed by compaction, showing a tendency to reduce pores. Mold pores and intergranular pores remain basically unchanged. According to the quantitative analysis of pore structure, each pore has a different evolutionary pattern. Macropores are the primary source of pore volume, micropores are the most active pore component in evolution, and mesopores exhibit a diminishing and then growing "U" shape characteristic. Three phases of tar-rich coal pore evolution—Ro, max < 0.9%, Ro, max = 0.9–3%, and Ro, max > 3%—can be distinguished, and there is a strong correlation between these stages and the coalification jumps.
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