Pinpointing the Cl Coordination Effect on Mn‐N3‐Cl Moiety Toward Boosting Reaction Kinetics and Suppressing Shuttle Effect in Li–S Batteries

Single atom catalysts (SACs) are highly favored in Li-S batteries due to their excellent performance in promoting the conversion of lithium polysulfides (LiPSs) and inhibiting their shuttling. However, the intricate and interrelated microstructures pose a challenge in deciphering the correlation between the chemical environment surrounding the active site and its catalytic activity. Here, a novel SAC featuring a distinctive Mn-N