化学
部分
氧化还原
超分子化学
两亲性
冠醚
组合化学
高分子化学
分子
有机化学
聚合物
共聚物
离子
作者
Bo Li,Qiangqiang Xu,Xin Shen,Tiezheng Pan,Jie Shang,Yan Gao,Zhenhui Qi
标识
DOI:10.1016/j.cclet.2022.108015
摘要
Control of self-assembly is significant to the preparation of supramolecular materials, but the control of hydration, responsiveness, dimension, catalysis of macrocyclic amphiphiles in an atom-economic manner is still a great challenge. The herein presented 527 Da low-molecular-weight macrocyclic amphiphile was fabricated by utilizing the selenium-containing crown ether as a hydrophobic motif together with guanidinium group as the hydrophilic moiety. The resulting benzo[21]crown-7 based macrocyclic amphiphile readily forms a redox-responsive solid nanoparticles in water, which can further interconnect into wrinkled pattern on-surface, as well as exhibits as a nanozyme for catalyzing disulfid bond formation. The present work highlights the great potential of guanidinium- and selenium-containing crown ethers for the control of functional assemblies.
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