Design, synthesis, and physicochemical study of a biomass-derived CO2 sorbent 2,5-furan-bis(iminoguanidine)

In this study, the concept of biomass-based direct air capture is proposed, and the aminoguanidine CO2 chemical sorbent 2,5-furan-bis(iminoguanidine) (FuBIG) was designed, synthesized, and elucidated for the physicochemical properties in the process of CO2 capture and release. Results showed that the aqueous solution of FuBIG could readily capture CO2 from ambient air and provided an insoluble tetrahydrated carbonate salt FuBIGH2(CO3) (H2O)4 with a second order kinetics. Hydrogen binding modes of iminoguanidine cations with carbonate ions and water were identified by single-crystal X-ray diffraction analysis. Equilibrium constant (K) and the enthalpies (ΔH) for CO2 absorption/release were obtained by thermodynamic and kinetic analysis (K7 = 5.97 × 104, ΔH7 = −116.1 kJ/mol, ΔH8 = 209.31 kJ/mol), and the CO2-release process was conformed to the geometrical phase-boundary model (1-(1-α)1/3 = kt). It was found that the FuBIGH2(CO3) (H2O)4 can release CO2 spontaneously in DMSO without heating. Zebrafish models revealed a favorable biocompatibility of FuBIG.