缝隙腐蚀
腐蚀
材料科学
冶金
放射性废物
金属
电化学
纳米晶材料
核化学
化学
电极
物理化学
纳米技术
作者
Tiankai Yao,Xiaolei Guo,Penghui Lei,Yachun Wang,G. S. Frankel,Jie Lian
标识
DOI:10.1038/s41529-020-0119-9
摘要
Abstract This paper studied the release of iodine from lead vanado-iodoapatite (I-APT, Pb 9.85 (VO 4 ) 6 I 1.7 ), a potential nuclear waste form for the radioactive waste element of I-129, which can be enhanced when crevice corrosion of stainless steel (SS) occurring nearby. Reference corrosion studies of I-APT were performed in different bulk solutions including DI water, 0.6 M and 6 M NaCl, and 0.1 M HNO 3 without metal crevice corrosion interactions. The localized enrichment of Cl − , one of the major consequences of SS crevice corrosion, was found to be the decisive factor that led to the enhanced release of iodine. A surface alteration layer consisting of a mixture of nanocrystalline I-APT and Cl-rich apatite (Cl-APT) formed on I-APT surface. Meanwhile, large Cl-APT crystals formed at the crevice mouth on the I-APT surface. This study reveals a new near-field corrosion mechanism for ceramic waste forms when they are exposed to aggressive local corrosive conditions created by the electrochemical reactions of nearby metals. The insight gained in this study could be beneficial for a more accurate prediction of waste form degradation.
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