The impact mechanism of Mn2+ ions on oxygen evolution reaction in zinc sulfate electrolyte

化学 析氧 电子转移 电解质 电化学 阳极 吸附 无机化学 氧化还原 化学工程 电极 物理化学 工程类
作者
Chenmu Zhang,Ning Duan,Linhua Jiang,Fuyuan Xu
出处
期刊:Journal of Electroanalytical Chemistry [Elsevier]
卷期号:811: 53-61 被引量:20
标识
DOI:10.1016/j.jelechem.2018.01.040
摘要

The impact mechanism of Mn2+ on the oxygen evolution reaction (OER) on the fresh lead-based anode in zinc sulfate electrolyte has been studied in detail by several electrochemical methods, XRD, SEM and EDX. The kinetics analysis suggested that the Mn2+ could significantly enhance OER, which was controlled by the electron transfer process between the active site S and H2O (step (2)). This positive effect of Mn2+ on OER was limited with the increase of Mn2+ because of the approaching saturation of active sites. Results obtained from the Arrhenius equation disclosed the larger bond strength of MnO2-OH in decreasing the activation energy of OER (from 55.08 to 47.04 kJ/mol), meanwhile, it also further supported the fact that the OER was electrochemical-controlled and it would not be changed in essence with the addition of Mn2+, which is subject to the activation energy barrier of electron transfer induced by the active site S (step (2)). EIS data revealed adsorption resistance of the intermediate (S-OHads), Ra played a major role among the whole reaction resistance, whereas, the impact contribution of charge transfer resistance, Rt became larger as the Mn2+ increases, which revealed that the inhibition of electron transfer process due to the changes of the anode surface microstructure. Electron microscope technology suggested the key role Mn2+ played in the modification of the active interface structure, and its influence process on OER was revealed by the microstructure analysis of anode surface. Considering the potential of Mn2+ concentration optimization in reducing heavy metal pollutants and energy consumption, enhancing the understanding of impact mechanism of Mn2+ on OER provides a feasible proposal in zinc electrolysis industry.

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
123完成签到,获得积分10
3秒前
赘婿应助渝安采纳,获得10
3秒前
张子捷应助sarah采纳,获得10
3秒前
4秒前
Sky关注了科研通微信公众号
4秒前
5秒前
6秒前
7秒前
ALONE完成签到,获得积分20
7秒前
曹沛岚完成签到,获得积分10
8秒前
张子捷应助weijiechi采纳,获得10
9秒前
fmwang发布了新的文献求助30
9秒前
wyg_gzed应助ss采纳,获得10
9秒前
王雪完成签到,获得积分10
10秒前
斯文听南发布了新的文献求助30
10秒前
11秒前
搜集达人应助ALONE采纳,获得10
11秒前
AYu发布了新的文献求助10
12秒前
Thunnus001完成签到,获得积分10
13秒前
shawn发布了新的文献求助10
14秒前
15秒前
Lucas应助范瑞文采纳,获得10
16秒前
20秒前
20秒前
ticsadis完成签到,获得积分10
23秒前
24秒前
TAO发布了新的文献求助10
25秒前
26秒前
26秒前
27秒前
赋成完成签到,获得积分10
28秒前
29秒前
秋天的向日葵完成签到 ,获得积分10
29秒前
彭珊发布了新的文献求助10
31秒前
31秒前
31秒前
小马甲应助追寻南珍采纳,获得10
32秒前
33秒前
迢迢笙箫应助彭珊采纳,获得10
35秒前
35秒前
高分求助中
The ACS Guide to Scholarly Communication 2500
Sustainability in Tides Chemistry 2000
Studien zur Ideengeschichte der Gesetzgebung 1000
TM 5-855-1(Fundamentals of protective design for conventional weapons) 1000
Threaded Harmony: A Sustainable Approach to Fashion 810
Pharmacogenomics: Applications to Patient Care, Third Edition 800
Genera Insectorum: Mantodea, Fam. Mantidæ, Subfam. Hymenopodinæ (Classic Reprint) 500
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3082549
求助须知:如何正确求助?哪些是违规求助? 2735847
关于积分的说明 7539036
捐赠科研通 2385432
什么是DOI,文献DOI怎么找? 1264844
科研通“疑难数据库(出版商)”最低求助积分说明 612830
版权声明 597685