光致发光
制作
空位缺陷
材料科学
共价键
无定形固体
吸附
化学工程
光电子学
纳米技术
结晶学
物理化学
化学
有机化学
医学
替代医学
病理
工程类
作者
Zhang Guo,Heying Yang,Qingyong Tian,Wenjie Ma,Qun Xu,Buxing Han
出处
期刊:ChemNanoMat
[Wiley]
日期:2022-08-09
卷期号:8 (10)
被引量:2
标识
DOI:10.1002/cnma.202200269
摘要
Two-dimensional (2D) non-van der Waals (non-vdW) amorphous nanomaterials have attracted much attention for optical, catalytic and biomedical applications owing to their rich dangling bonds and unsaturated coordination. CeO2, a typical non-vdW material, with amorphous 2D structure and intrinsic optical properties have rarely been prepared via a top-down method due to the lack of anisotropy in its 3D bonding network. Herein, we develop an environmentally-friendly top-down method to achieve ultrathin 2D amorphous CeO2−x with controllable defects from bulk CeO2 by utilizing supercritical CO2. The unique CeO2−x nanosheets exhibit outstanding ultraviolet-visible adsorption and photoluminescence (PL) properties due to the disordered atomic structure and increased vacancy defects resulting from the cleavage of Ce−O covalent bonds and amorphization of CeO2. In addition, the defect-related emission mechanism of the visible PL for the as-prepared 2D CeO2−x nanosheets has been proposed.
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