石膏
弹性(物理)
水合硅酸钙
材料科学
矿物学
化学工程
化学
复合材料
水泥
工程类
作者
Tingjie Huang,Qiang Yuan,Shenghao Zuo,Youjun Xie,Caijun Shi
标识
DOI:10.1016/j.cemconres.2022.106860
摘要
Gypsum has been known to regulate cement setting since more than 100 years, whereas the understanding of the physio-chemical mechanism remains incomplete. Here, we investigated the influence of gypsum on elasticity evolution of fresh tricalcium silicate (C3S) paste through small amplitude oscillation shear method. Isothermal calorimetry, X-ray diffraction, 1H nuclear magnetic resonance, and zeta potential measurements were performed to explore the corresponding changes in hydration, microstructure, and colloidal interaction. It was found that incorporating gypsum is beneficial for inter-particle agglomeration by significantly weakening electrostatic repulsion force between particles, which accelerates elasticity development in the early period of setting. Although the retardation effect of gypsum on C3S hydration hinders the further development of elasticity in the later period, the more divergent needle-like calcium silicate hydrate (C-S-H) and the stronger cohesion of the C3S particle network in presence of gypsum lead to a higher elasticity at the same hydration degree.
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