降冰片烯
共聚物
高分子化学
嬉戏
聚合
复分解
异氰
侧链
开环聚合
化学
材料科学
聚合物
有机化学
作者
Zhiqiang Jiang,Yaxin Xue,Jiali Chen,Zhipeng Yu,Na Liu,Jun Yin,Yuan‐Yuan Zhu,Zong‐Quan Wu
出处
期刊:Macromolecules
[American Chemical Society]
日期:2014-12-22
卷期号:48 (1): 81-89
被引量:45
摘要
An air-stable phenylethynyl Pd(II) complex containing a polymerizable norbornene unit was designed and synthesized. Such a Pd(II) complex can initiate the living/controlled polymerization of phenyl isocyanide, giving stereoregular poly(phenyl isocyanide)s in high yields with controlled molecular weights and narrow molecular weight distributions. The norbornene unit on the Pd(II) complex can undergo ring-opening metathesis polymerization (ROMP) with Grubbs' second-generation catalyst, affording polynorbornene bearing Pd(II) complex pendants under a living/controlled manner. Interestingly, the Pd(II) complex pendants on the isolated polynorbornene are active enough to initiate the living/controlled polymerization of phenyl isocyanides, yielding well-defined brush-like copolymers with polynorbornene backbone and helical poly(phenyl isocyanide) as side chains. 31P NMR analyses indicate almost all the Pd(II) units on the polynorbornene participated in the polymerization, and the grafting density of the brush copolymer is high. Further studies revealed the brush copolymer can be readily achieved in one-pot via tandem catalysis. By using this method, a range of brush copolymers with different structures and tunable compositions were facilely prepared in high yields with controlled molecular weights and narrow molecular weight distributions. The synthesized brush copolymers were revealed to form worm-like cylindrical morphologies and helical rod architectures in film state by atomic force microscope observations.
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