3D graphene decorated NaTi2(PO4)3 (NTP@rGO) is successfully synthesized through a facile spray-drying method. This NTP@rGO material can deliver high reversible capacity (130 mAh g−1 at 0.1 C), superior high-rate rate capability (38 mAh g−1 at 200 C) and long cycling stability (77% capacity retention after 1000 cycles), suggesting its applicability as a high rate and cycle-stable anode for the development of high-power and long cycle life sodium ion batteries for energy storage applications. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.