聚对苯二甲酸乙二醇酯
阳极
材料科学
傅里叶变换红外光谱
对苯二甲酸二甲酯
化学工程
离子
电极
有机化学
复合材料
化学
物理化学
聚酯纤维
工程类
作者
Sourav Ghosh,Maxim A. Makeev,Zhimin Qi,Haiyan Wang,Nav Nidhi Rajput,Surendra K. Martha,Vilas G. Pol
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2020-03-15
卷期号:8 (16): 6252-6262
被引量:48
标识
DOI:10.1021/acssuschemeng.9b07684
摘要
In this work, we report an efficient synthesis approach of disodium terephthalate and its application as a potential battery anode material. Disodium terephthalate is upcycled from waste polyethylene terephthalate flakes with the aid of an ultrafast microwave irradiation process within 2 minutes. The phase and chemical purity of the as-synthesized disodium terephthalate is confirmed by X-ray diffraction, Fourier-transform infrared spectroscopy, and nuclear magnetic resonance spectroscopy. The electrochemical behavior of this low-cost, environmentally benign organic molecular compound is studied in Li- and Na-ion cells. The density functional theory-based calculations are performed to get insights into specifics of electronic properties of Li- and Na-ion cells and rationalize the differences in behavior for the two systems. The delithiation potential of a disodium terephthalate anode is found to be approximately 0.65 V higher than the desodiation potential. The disodium terephthalate-carbon black (Super P) composite electrode delivers discharge capacities of 182 and 224 mAh g–1 at a current density of 25 mA g–1 after 50 cycles in Li-ion and Na-ion cells, respectively. The better C-rate performance of the composite anode for a Li-ion cell, as compared to a Na-ion cell, is due to inferior mobility of Na-ions in the electrode material, which is largely defined by ion size.
科研通智能强力驱动
Strongly Powered by AbleSci AI