异质结
材料科学
电化学
化学工程
原位
相(物质)
基质(水族馆)
拉曼光谱
析氧
纳米技术
电极
化学
光电子学
物理化学
海洋学
有机化学
工程类
地质学
物理
光学
作者
Wenda Zhang,Qing‐Tao Hu,Linlin Wang,Jie Gao,Haiyan Zhu,Xiaodong Yan,Zhi‐Guo Gu
标识
DOI:10.1016/j.apcatb.2021.119906
摘要
Engineering the abundant phase interface in hybrid materials for high electrocatalytic activity is an effective strategy to enhance the electrochemical performance. In this work, Ni-MOF/Ox-MOF is constructed through the “growth of MOF on MOF” strategy. Following with in-situ conformal transformation in alkaline solutions, Ni-MOF/LDH heterostructures are fabricated, which exhibit excellent water oxidation activity owing to the high surface area of Ni-MOF substrate and the well-tailored phase interfaces. In addition, the high stability of Ni-MOF/LDH is demonstrated in a Zn-air battery. In-situ Raman technique identifies that the Ni centers are the true active sites during water oxidation. DFT calculations demonstrate that the charge transfer and the conductivity at the Ni-MOF/LDH interfaces is highly enhanced. This work provides an efficient method of fabricating MOF/LDH heterostructures with optimized phase interfaces and offers new insights into OER.
科研通智能强力驱动
Strongly Powered by AbleSci AI