硫酸盐
铁质
热分解
化学
四水合物
硫酸铁
酸洗
无水的
热重分析
炼钢
无机化学
硫酸钠
氧化铁
冶金
材料科学
钠
结晶学
有机化学
晶体结构
作者
Ndue Kanari,Nour‐Eddine Ménad,Etleva Ostrosi,Seit Shallari,Frédéric Diot,Eric Allain,Jacques Yvon
出处
期刊:Metals
[MDPI AG]
日期:2018-12-19
卷期号:8 (12): 1084-1084
被引量:43
摘要
Iron sulfate, in particular FeSO4·7H2O, is derived from titanium dioxide production and the steel pickling process. Regarding TiO2 manufacturing, the amount of the resultant FeSO4·7H2O can be as high as 6 tons per ton of produced TiO2, leading to a huge amount of ferrous sulfate heptahydrate, which is considered an environmental and economic concern for the titanium dioxide industry in European countries. The present paper focuses on the thermal treatment of ferrous sulfate (heptahydrate and monohydrate) samples under different conditions. Nonisothermal thermogravimetric (TG) analysis was used to study the behavior of iron sulfate samples at temperatures of up to 1000 °C in Cl2 + O2, O2, and N2 atmospheres. Results showed that the dehydration of iron sulfate heptahydrate in nitrogen started at room temperature and resulted in iron sulfate tetrahydrate (FeSO4·4H2O). The ferrous sulfate monohydrate (FeSO4·H2O) was formed at temperatures close to 150 °C, while the anhydrous ferrous sulfate (FeSO4) was obtained when the samples were heated in nitrogen at over 225 °C. The kinetic features of FeSO4 decomposition into Fe2O3 were revealed under isothermal conditions at temperatures ranging from 500 to 575 °C. The decomposition of iron sulfate was characterized by an apparent activation energy of around 250 kJ/mol, indicating a significant temperature effect on the decomposition process. The obtained powder iron oxide could be directed to the agglomeration unit of iron and the steelmaking process.
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