普鲁士蓝
纳米棒
吸附
热液循环
亚甲蓝
铯
化学工程
材料科学
原位
混合材料
水热合成
碳纤维
化学
无机化学
核化学
纳米技术
有机化学
电化学
电极
复合数
催化作用
复合材料
物理化学
光催化
工程类
作者
Shangqing Chen,Deyun Sun,Lei Zou,Yi Huang,F.T. Cheng,Lijuan Shi,Abdullah Tasleem,Atta Ullah,Syed Sheraz Daood,Qun Yi
标识
DOI:10.1016/j.cej.2024.153457
摘要
Prussian blue analogues (PBAs) are recognized as effective and selective adsorbents for Cs+, however, they suffered from unsatisfactory post-separation performance and inevitable dissolution loss arising from the small size and inferior water instability. In this study, Zn-PBA nanoparticles were integrated onto polymeric carbon nitride (PCN) nanorods to form PBA-PCN hybrid via hydrothermal pre-anchoring and in-situ growth method. The robust and amino-rich PCN played dual roles in securely anchoring the Zn2+ precursor and attracting Cs+ to the surface. Benefiting from the effects of PCN and in-situ generated PBA, PBA-PCN exhibited boosting post-separation performance and water stability in acid and alkaline solutions, which was attractive in different application scenarios. Moreover, PBA-PCN has been demonstrated to be with high adsorption capacity of 376.41 mg/g and favorable selectivity even in the presence of excessive competitive ions. The experimental results and DFT calculations suggested the adsorption mechanism involving strong incorporation/ion exchange and weak electrostatic attraction. The remarkable adsorption performance along with the satisfactory post-separation performance and water stability made it a promising candidate in Cs+ removal and separation.
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