材料科学
纳米颗粒
五元
合金
燃烧
化学工程
热解
粒径
氧化物
催化作用
烧结
粒子(生态学)
纳米技术
冶金
有机化学
化学
工程类
海洋学
地质学
作者
Yifan Dai,Jie Ju,Luo Liling,Hao Jiang,Yanjie Hu,Chunzhong Li
标识
DOI:10.1002/smtd.202301768
摘要
Abstract The synthesis of high‐entropy alloys (HEAs) with ultra‐small particle sizes has long been a challenging task. The complex and time‐consuming synthesis process hinders their practical application and widespread adoption. This study presents the novel synthesis of TiO 2 nanoparticles loaded with a quinary high‐entropy alloy through flame spray pyrolysis (FSP) for the first time. The extremely fast heating rate of flame combustion makes the precursor fast pyrolysis gasification, high temperature in the flame field promotes the metal vapor mixing uniformly, and the fast quenching process can reduce the particle aggregation sintering, the ultra‐small particle size of HEA firmly attached to the TiO 2 surface. The catalysts prepared via this gas‐to‐particle pathway exhibit excellent performance in CO 2 hydrogenation, achieving a conversion rate of 62% at 450 °C, and maintaining their activity for over 220 h without significant particle agglomeration. This finding provides valuable insights for the future design of catalytically active materials with enhanced activity and long‐term stability.
科研通智能强力驱动
Strongly Powered by AbleSci AI