分离器(采油)
材料科学
复合数
储能
化学工程
多孔性
锂硫电池
电化学
电化学储能
电池(电)
共价键
纳米技术
复合材料
化学
电极
超级电容器
有机化学
物理
工程类
物理化学
功率(物理)
热力学
量子力学
作者
Bingxin Jia,Hongmin Yu,Zhao Wang,Chan Yao,Wei Xie,Nan Jiang,Shu-Ran Zhang,Yan-Hong Xu,Hao Sun,Ning Huang
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2024-05-09
卷期号:6 (10): 5910-5919
被引量:2
标识
DOI:10.1021/acsapm.4c00572
摘要
With the depletion of fossil energy and increasingly serious environmental pollution, the development of renewable sources of energy is imminent. Exploration of high-efficiency energy storage and transformation materials has become the focus in the field of energy research. Covalent organic frameworks (COFs), as a kind of porous and crystalline polymer, have attracted extensive attention. In this work, we developed a composite material (Al2O3-G-COFSO3) using COFs and alumina, which can serve as an efficient separator in lithium–sulfur (Li–S) batteries. In the composite, alumina can improve the transport ability of Li+ and thus improve conductivity and SO3–COF can effectively restrain the shuttle of polysulfides by electrostatic repulsion. At a current density of 0.05C, the composite-based battery exhibited a high capacity of 1404 mAh g–1, which ranks as one of the highest values among all of the COF-based Li–S batteries. Even at a discharge rate of 1C, it can also achieve a high experimental capacity of 999 mAh g–1 with a low decay rate of 0.061% over 500 cycles. Moreover, the battery also showed a high electrochemical stability and long-term performance stability.
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