压电
层状结构
材料科学
结晶度
压电传感器
相(物质)
碳纳米管
复合材料
有机化学
化学
作者
Ming Liang,Jianjiang Wang,Linping Su,Xin Xue,Zhenchao Chen,Yunfeng Zhang,Yuepeng Jiao,Cong Qi,Yuxiang Wu,Zhanyong Yao
标识
DOI:10.1016/j.cej.2024.154554
摘要
Active monitoring and accurate sensing of road traffic information provide crucial data for road managers and traffic law enforcement. However, current sensors and monitoring systems struggle to capture comprehensive vehicle information simultaneously. In the study, a novel piezoelectric sensor using PVDF/PZT/CNTs composites was developed for actively monitoring road traffic information and explored for energy harvesting suitability. Piezoelectric composites with a lamellar wrapped structure and excellent localized conductive networks were prepared through solution blending, non-solvent-induced phase separation, and layered hot pressing. The results revealed that this structural design improves the proportions, crystallinity, and content of the β-phase crystals in the composites, while significantly enhancing their piezoelectric properties, dielectric properties, and electronegativity. When the content of CNTs was 3.0 wt%, the proportion and content of β-phase crystals in the composites reached the highest values (91.36 % and 62.34 %), respectively. Additionally, the open-circuit voltage (Voc) and the short-circuit current (Isc) were 3.36 and 6.16 times higher, respectively, than those of the undoped CNTs composites. The developed piezoelectric sensor shows a wide pressure monitoring range (0.1 MPa–2.1 MPa), excellent sensitivity (6.94 MPa−1 at (<0.6 MPa) and 12.35 MPa−1 at (0.6–2.1 MPa)). As a vehicle non-stop weighing sensor, it presents extremely fast response (15 ms) and recovery (16 ms) speeds with long-term stability of 500,000 cycles. The most important feature of the developed piezoelectric sensor is its dual function as both a sensor and an energy harvester. Furthermore, the developed piezoelectric sensor can actively monitor vehicle axle weight, speed, and wheelbase while capturing energy from vehicle movement. This work opens up innovative solutions for road traffic monitoring and vehicle movement energy harvesting, with promising applications in intelligent transportation.
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