材料科学
联氨(抗抑郁剂)
海水
电解
电催化剂
过电位
电化学
电解水
制氢
化学工程
无机化学
氢
物理化学
海洋学
有机化学
电极
电解质
地质学
工程类
化学
色谱法
作者
Haoyu Wang,Fengxiao Yan,Hao Wang,Sixiang Zhai,Jin‐Tao Ren,Lei Wang,Minglei Sun,Zhong‐Yong Yuan
标识
DOI:10.1002/aenm.202402611
摘要
Abstract The utilization of hydrazine in aiding water electrolysis presents a promising avenue for achieving highly efficient hydrogen production through energy conversion. Herein, bifunctional electrocatalyst of urchin‐like iron, nickle‐codoped cobalt phosphide supported on Ni foam (FeNi‐CoP/NF) is reported. Benefitting from the combined electronic structure and lattice strain engineering by Fe and Ni‐ codoping, the hydrazine‐assisted seawater electrolysis assembled with FeNi‐CoP/NF as both electrodes can achieve an industrial‐level current density of 1.5 A cm −2 at a record‐setting voltage of 163 mV at 70 °C and sustain stable operation for hundreds of hours in seawater environment. The existence of a potential coincidence region lends credibility to the feasibility of implementing self‐activated hydrazine‐assisted seawater electrolysis. Based on theoretical calculations, the separate and synergistic effects of electronic structure and lattice strain engineering are investigated and an integrated illustration of these two strategies on enhancing hydrogen evolution and hydrazine oxidation activity is provided. Moreover, an innovative multi‐powered hydrogen generation system featuring a direct hydrazine fuel cell, rechargeable Zn‐hydrazine battery, and hydrazine‐assisted seawater electrolysis is proposed, underscoring the unique advantages of hydrazine oxidation reaction and its prospective contribution to electrochemical energy conversion technologies powered by sustainable sources.
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