Investigating the impact of growth time of CdSe quantum dots on the structure and optical properties of its nanocomposites with SiO2 for improvement of optical devices

This study effectively succeeded in synthesizing CdSe QDs and CdSe- SiO 2 nanocomposites with controllable tunable size and spectacular morphology by using a solvothermal technique. UV-visible spectroscopy was used to study the effect of the growth time of CdSe QDs on the optical properties of its nanocomposite with SiO 2 . The structure of the prepared nanocomposites of CdSe- SiO 2 was studied through the measurements of X-ray diffraction (XRD), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy FTIR. The Effective Mass Approximation model (EMA), Simple Exponential Function (SEF), and Polynomial Fitting Functions (PFF) were employed to compute nanoparticle sizes, providing particle sizes of 3.86, 4.19, and 3.72 nm, respectively, for CdSe- SiO 2 nanocomposites (2 minutes). For the same nanocomposite, these theoretical values were comparable to the experimental values of the particle sizes deduced from measurements of TEM (4.5 nm) and XRD (3.4 nm). The deduced optical parameters of CdSe-SiO 2 nanocomposite, such as refractive index, dielectric constant, optical conductivity, electrical susceptibility, and some others, relied on the growth time of CdSe QDs. The absorption peaks of CdSe -SiO 2 nanocomposites suffered from a bathochromic shift which increases as the growth time of CdSe QDs increases. Increasing the growth time of CdSe QDs resulted in increasing the reflection loss factor and decreasing the optical electronegativity. The values of the volume energy loss function (VELF) are greater than the values of the surface energy loss function (SELF) for the different nanocomposites. Consequently, the fast electrons miss their energies through their propagation within the studied materials more than through travelling on their surfaces. The enhancement of n values of nanocomposites of CdSe-SiO 2 by increasing the growth time can candidate them to be usefully applied as antireflection coating for solar cells. • Modify the structure and enhance the optical properties of CdSe-SiO 2 nanocomposites depending on the growth time of CdSe QD. • Coincidence between theoretical values of particle size and the experimental values deduced from XRD and TEM analysis. • Understanding the structure of the produced nanocomposites by FTIR analysis.