稀释剂
高分子化学
氯乙烯
共聚物
聚合
单体
动力学
乳液聚合
自由基聚合
化学
活性自由基聚合
材料科学
有机化学
聚合物
量子力学
物理
出处
期刊:Advances in Polymer Science
日期:1995-01-01
卷期号:: 135-205
被引量:6
标识
DOI:10.1007/3-540-58704-7_3
摘要
The aim of this review is to summarize and discuss the kinetic data of the emulsion polymerization and copolymerization of vinyl chloride. The current understanding of the kinetics of free-radical polymerization of conventional monomer is briefly described and kinetic data of radical polymerization and copolymerization of vinyl chloride in the presence of hydrophobic and hydrophilic additives are summarized. Effects of the initiator type and concentration, the reaction conditions and the type of diluent are evaluated. Variation of kinetic and molecular weight parameters in the heterogeneous polymerizations with emulsifier type and concentration are discussed.
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