Ce-doped copper oxide and copper vanadate Cu3VO4 hybrid for boosting nitrate electroreduction to ammonia

The electrocatalytic nitrate reduction to ammonia reaction (ENO3RR) holds great potential as a cost-effective method for synthesizing ammonia. This work designed a cerium (Ce) doped Cu2+1O/Cu3VO4 catalyst. The coupling of vanadium-based oxides with Cu2+1O effectively adjusts the catalyst's electronic structure, addressing the inherent issues of limited activity and low conductivity in typical copper-based oxides; moreover, Ce doping generates oxygen vacancies (Ov), providing more active sites and thereby enhancing the ENO3RR performance. The catalyst exhibits superior NH3 Faradaic efficiency (93.7 %) with a NH3 yield of 18.905 mg h−1 cm−2 at −0.5 V vs. RHE under alkaline conditions. This study provides guidance for the design of highly efficient catalysts for ENO3RR.