Promoted electrochemical performance by MOF on MOF composite catalyst of microbial fuel cell: CuCo-MOF@ZIF-8 and the comparison between two-step hydrothermal method and dual-solution method

The microbial fuel cell (MFC) is a device that simultaneously achieves electricity generation and sewage degradation. In this study, a novel cathode catalyst metal-organic frameworks (MOFs) have been fabricated by two-step hydrothermal and dual-solution method (CuCo-MOF@ZIF-8). The synthesized trimetal MOFs exhibited a 3D badminton-like structure morphology and porosity. The results of the characterizations showed that CuCo-MOF@ZIF-8 possesses greater surface area porosity and novel functional groups. The Trimetal MOF-on-MOF mode not only demonstrated the stability of the structure but also enhanced its mechanism. Molecular mechanism analysis revealed changes in the organic ligand and metal binding site due to the transformation of Cu