超级电容器
普鲁士蓝
材料科学
介孔材料
功率密度
阴极
储能
纳米技术
电化学
化学工程
电极
电容
化学
功率(物理)
催化作用
有机化学
工程类
物理化学
物理
量子力学
作者
Yangming Shi,Pinghua Chen,Jiezeng Chen,Dezhi Chen,Hongying Shu,Hualin Jiang,Xubiao Luo
标识
DOI:10.1016/j.cej.2020.126284
摘要
Supercapacitors are highly promising energy storage/conversion devices owing to their outstanding advantages such as high power density, long operational life, flash charge/discharge speed, and low cost. However, the low energy density is the bottleneck limiting their wide application. Acquirement of high-performance supercapacitors with ultrahigh energy density closed to batteries’ is still a challenge. In this study, a mesoporous hollow Prussian blue analogues (PBA) nano-box/g-C3N4 hybrid was successfully synthesized. It shows excellent electrochemical performance with a high specific capacity of 201.6 mAh g−1 and outstanding cycling stability (90.1% capacity retention after 5,000 cycles), which are significantly higher than those of most other PB/PBA based electrode materials. Furthermore, it was coupled with active carbon to construct an all-solid-state asymmetric supercapacitor denoted as H Rb-NiHCF/g-C3N4//AC, which exhibits a high energy density of 46.9 Wh kg−1 at the power density of 808.2 W kg−1, which is closed to that of commercial Ni/MH batteries. It also shows good cycling stability. Furthermore, it can easily light up a LED indicator and efficiently work for more than 3 min. This mesoporous hollow PBA nano-box/g-C3N4 hybrid demonstrates its high practical potential for cathode materials in high-performance supercapacitors.
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