检出限
化学
色谱法
重复性
固相萃取
邻苯二甲酸盐
萃取(化学)
高效液相色谱法
有机化学
作者
Qiuhua Wu,Yuhong Song,Qianqian Wang,Weihua Liu,Lin Hao,Zhi Wang,Chun Wang
出处
期刊:Food Chemistry
[Elsevier]
日期:2020-08-17
卷期号:339: 127855-127855
被引量:68
标识
DOI:10.1016/j.foodchem.2020.127855
摘要
A magnetic o-hydroxyazobenzene (M-HAzo) porous organic polymer was facilely prepared by a green azo coupling reaction in aqueous solution. The prepared M-HAzo was applied as a new adsorbent for the first time to pre-concentrate phthalate esters (PAEs) from plastic bottled juice, followed by their determination with high performance liquid chromatography-ultraviolet detection. The effects of various parameters, i.e., the mass ratio of the Fe3O4@SiO2 to HAzo, extraction time, ionic strength, pH of the sample, desorption conditions were optimized. Under the optimized conditions, the M-HAzo based method exhibited good performance in terms of linear range (0.3–50.0 μg L−1), detection limit (0.08–0.50 μg L−1), accuracy (recovery of 78.0–115.0%) and repeatability (relative standard deviation of 2.9–7.8%). This work provides a sensitive method for analysis of PAEs at trace levels in drinks, which is featured with high sensitivity, simple operation and environmentally-friendly merit and will have a promising potential in analysis of other organic pollutants.
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