A new sesquiterpenol was isolated from santalwood oil (Santalum album L., Santalaceae). Its structure and relative stereochemistry were elucidated on the basis of spectral analysis (IR, MS, 1H-1H COSY, 13C-1H COSY and 1H-1H NOESY) as 9(10)Z, alpha-trans-bergamotenol (Ia).