盐(化学)
溶剂
锂(药物)
电解质
扩散
离子电导率
乙腈
电导率
离子键合
聚合物
化学
材料科学
化学工程
无机化学
高分子化学
有机化学
热力学
离子
物理化学
医学
工程类
内分泌学
物理
电极
作者
Maritza Volel,Michel Armand,W. Gorecki
出处
期刊:Macromolecules
[American Chemical Society]
日期:2004-09-28
卷期号:37 (22): 8373-8380
被引量:38
摘要
We provide clear evidence of the effect of the solvent used for sample preparation on the morphology and transport properties of PEO−lithium salt (LiTFSI, LiBF4, or LiClO4) complexes. The surface structure, thermal behavior, and conductivity of the films along with the measured diffusion coefficients and transport numbers of the ionic species are clearly different whether acetonitrile (good solvent of PEO) or methyl formate (poor solvent) was used. Interestingly, the samples with the lowest conductivity have the highest diffusion coefficients, indicative of a difference in carriers concentration. We infer that the polymer chains keep memory of the solvent, and their generated spatial organization is directly implied in conductivity through the use of specific pathways for ionic mobility. Since the variations observed here are of the same amplitude or greater than those observed for some deliberate modification of the polymer electrolytes (i.e., nanoparticles addition, mechanical strain, etc.), great care must now be exercised in giving precise sample history.
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