钨
拉曼光谱
X射线光电子能谱
碱金属
氧气
雅恩-泰勒效应
材料科学
八面体
兴奋剂
结晶学
无机化学
离子
晶体结构
化学
分析化学(期刊)
核磁共振
物理
光学
有机化学
冶金
光电子学
色谱法
作者
Mika Okada,Katsushi Ono,Satoshi Yoshio,Hideaki Fukuyama,Kenji Adachi
摘要
Abstract Structural and compositional changes of Cs‐doped hexagonal tungsten bronzes ( HTB ) with respect to variations in oxygen deficiency and alkali content have been investigated in detail through x‐ray diffraction Rietveld analysis, x‐ray photoelectron spectroscopy, and Raman spectroscopy. Cs‐ HTB crystallized in a reductive atmosphere is evidenced to generally contain plenty of oxygen defects, and a general formula, Cs x WO 3− y (0.20 ≤ x ≤ 0.32, 0 < y ≤ 0.46), is proposed. Lattice parameters of Cs‐ HTB are observed to vary according to the relation, c (Å) = −3.436 a (Å) + 33.062. The coordinated modification of W–O octahedral dimensions suggests the origin of the structural change with increasing x and y to be a destabilization of the pseudo Jahn‐Teller distortion due to donated electrons. The dimensional change of lattice due to electrons emitted from oxygen defects is appraised only 1/18 as that due to electrons from doped alkali ions, suggesting that most electrons from oxygen defects should be localized in Cs‐ HTB .
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