Boosting interfacial solar steam generation by three-dimensional bilayer cellulose aerogels

Interfacial solar steam generation (ISSG) provides a sustainable approach of clean water production through desalination and water purification. It is still needed to pursue a fast evaporation rate, high-quality freshwater production, and low-cost evaporators. Herein, a three-dimensional (3D) bilayer aerogel was fabricated using cellulose nanofiber (CNF) as a skeleton filled with polyvinyl alcohol phosphate ester (PVAP), and carbon nanotubes (CNT) as a light absorbing material in the top layer. The CNF/PVAP/CNT aerogel (CPC) had broadband light absorption ability and exhibited an ultrafast water transfer rate. The lower thermal conductivity of CPC effectively confined the convert heat in the top surface and minimized heat loss. Additionally, a large amount of intermediate water caused by water activation decreased the evaporation enthalpy. Under 1 sun irradiation, the CPC-3 (3.0 cm height of CPC) achieved a high evaporation rate of 4.02 kg m-2 h-1 with an energy conversion efficiency of 125.1%. The additional convective flow and environmental energy made CPC achieve an ultrahigh evaporation rate of 11.37 kg m-2 h-1, surpassing 673% of the solar input energy. More importantly, the continuous solar desalination and higher evaporation rate (10.70 kg m-2 h-1) in seawater revealed that CPC was a promising candidate for practical desalination. Outdoor cumulative evaporation was up to 73.2 kg m-2 d-1 in weak sunlight and lower temperature, which would meet the daily drinking water demands of 20 people. The excellent cost-effectiveness of 1.085 L h-1 $-1 presented its potential for a wide range of practical applications, such as solar desalination, wastewater treatment, and metal extractions.