有机太阳能电池
光降解
光伏系统
材料科学
纳米技术
化学
工程类
催化作用
电气工程
光催化
光化学
有机化学
作者
Han Xu,Jianhua Han,Si Chen,Ye Liu,Luis Huerta Hernandez,Jules Bertrandie,Maxime Babics,Shahidul Alam,Diego Rosas Villalva,Sri Harish Kumar Paleti,Julien Gorenflot,Christoph Herok,Nicolás Ramos,Joel Troughton,Anirudh Sharma,Todd B. Marder,Bernd Engels,Jaime Martín,Stefaan De Wolf,Frédéric Laquai,Derya Baran
出处
期刊:Joule
[Elsevier]
日期:2023-07-24
卷期号:7 (9): 2135-2151
被引量:20
标识
DOI:10.1016/j.joule.2023.07.003
摘要
Despite striking progress toward improving the photovoltaic (PV) performance of organic solar cells (OSCs) with recent Y-series non-fullerene acceptors (Y-NFAs), knowledge about their outdoor performance under real-world conditions and photodegradation mechanisms remains elusive, which is urgently needed to close the lab-to-fab gap of OSCs. Herein, for the first time, we study the structure-outdoor-stability relationship of Y-NFAs. We show that Y-NFAs with long internal side-chains exhibit high energy barriers for photoisomerization, and fluorinated end-groups can enhance the structural confinement to inhibit the photodegradation pathway and thereby improve device stability. Furthermore, the performance loss of Y-NFA-based OSCs under illumination is mainly driven by increased trap-assisted recombination over time. The structure-stability correlation and demonstration of outdoor performance of these state-of-the-art Y-NFA cells provided in this study highlight molecular engineering of device stability control to minimize power output losses in real-world climates.
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