Facile Synthesis of a Layered Bismuth‐Based MOF With Superhydrophobic–Oleophilic Property and High Oil–Water Separation Performance

Abstract Metal organic frameworks (MOFs) are a class of potential superhydrophobic–oleophilic materials. The organic ligands in superhydrophobic MOFs usually contain long alkyl chains, fluorine groups or aromatic rings with large π conjugation, the preparation of which suffers from high cost, complex operation and so on. In addition, the topological structure of MOFs plays an important role in the hydrophobicity, which may be ignored previously. Here we report a superhydrophobic–oleophilic MOF (BiPPA 2 ) obtained by a facile and fast method, which not only displays a large water contact angle of up to 163° and a small sliding angle of nearly equal to 0°, but also exhibits high sorption capacity for multiple oils and organic solvents, well reusability and high oil retention. In addition, BiPPA 2 is stable in a wide pH range (0.5–11.0). Finally, the single crystal structure of BiPPA 2 is resolved to reveal the intrinsic reason for the super‐hydrophobicity. This work may inspire the further design of pristine superhydrophobic MOFs based on a simple method, which enriches the family of superhydrophobic MOFs and has great significance for practical applications.