Stereoselective Synthesis of ( Z )‐β‐Thioenamide from ( Z )‐Enamide‐iodines and Thiols under Mild Conditions

The (Z)‐β‐thioenamides is a valuable motif in many drugs. However, it’s stereoselective synthesis is still facing challenge. Herein, we firstly reported a general and efficient approach for highly stereoselective synthesis of them by using (Z)‐enamide‐iodines with thiols under transition metal‐free conditions.