Amine‐Functionalized Amyloid Aerogels for CO2 Capture

Abstract Climate change caused by excessive CO 2 emissions constitutes an increasingly dire threat to human life. Reducing CO 2 emissions alone may not be sufficient to address this issue, so that the development of emerging adsorbents for the direct capture of CO 2 from the air becomes essential. Here, we apply amyloid fibrils derived from different food proteins as the solid adsorbent support and develop aminosilane‐modified amyloid fibril‐templated aerogels for CO 2 capture applications. The results indicate that the CO 2 sorption properties of the aerogels depend on the mixing ratio of aminosilane featuring different amine groups and the type of amyloid fibril used. Notably, amine‐functionalized β ‐lactoglobulin (BLG) fibril‐templated aerogels show the highest CO 2 adsorption capacity of 51.52 mg (1.17 mmol) CO 2 /g at 1 bar CO 2 and 25.5 mg (0.58 mmol) CO 2 /g at 400 ppm; similarly, the CO 2 adsorption capacity of chitosan‐BLG fibril hybrid aerogels is superior to that of pure chitosan. This study provides a proof‐of‐concept design for an amyloid fibril‐templated hybrid material facilitating applications of protein‐based adsorbents for CO 2 capture, including direct air capture.