异山梨酯
环氧树脂
极限抗拉强度
材料科学
热固性聚合物
固化(化学)
聚合物
热稳定性
胺气处理
缩水甘油醚
高分子化学
有机化学
复合材料
化学
双酚A
作者
Ruohan Yang,Weijie Li,Ruibin Mo,Xinya Zhang
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2023-10-09
卷期号:5 (11): 9395-9402
标识
DOI:10.1021/acsapm.3c01879
摘要
A series of recyclable biobased dynamic cross-linking epoxy polymers containing vinylogous urethane bonds (ISVUEs) were constructed under solvent-free conditions by using diglycidyl ether of isosorbide and isosorbide-bis-acetoacetate derived from biobased isosorbide and cured with trifunctional and difunctional primary amines. The influence of amine curing agents and dynamic bond contents on the cross-linking density, thermal stability, and tensile and recycle properties of ISVUEs was investigated. The results showed that triamine as the cross-linker endowed a significant effect on the properties of ISVUEs. The tensile strength of the polymer with tris (2-aminoethyl) amine as the triamine reached 40.3 MPa, with only a small increase in tensile strength in three recycling cycles. The polymer with polyetheramine T403 as the triamine showed an elongation at break of 171.9% and a shape recovery of up to 84.5%, which exhibited a good shape memory effect. Meanwhile, the ISVUEs exhibit good recyclable properties when the amount of dynamic bond content is 66.7%. The design provides a strategy for introducing vinylogous urethane bonds into biobased epoxy polymers with potential smart applications such as textiles, medical implants, and soft robotics.
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