Sight into a Rare-Earth-Based Catalyst with Spatial Confinement Effect from the Perspective of Electronic Structure

Rare-earth elements include 15 kinds of lanthanides as well as Sc and Y elements. Interestingly, the special electronic configuration of a lanthanide rare earth is [Xe]4fn5d0–16s2 (n = 0–14), which results in rare-earth materials' unique activity in such areas as thermal catalysis, electrocatalysis, photocatalysis, etc. It is worth noting that a class of materials with spatial confinement effects are playing an increasingly important role in the catalytic performance; especially, the construction of hollow multishelled structures (HoMSs) can further enhance the activity of rare-earth catalytic materials. In this review, we discuss in depth the important roles of the rare-earth 4f5d electronic structure. Subsequently, this review systematically summarizes the synthesis methods of rare-earth HoMSs and their research progress in the field of catalysis and specifically introduces the advanced characterization and analysis methods of rare-earth HoMSs. Finally, the research directions, application prospects, and challenges that need to be focused on in the future of rare-earth-based HoMSs are discussed and anticipated. We believe that this review will not only inspire more creativity in optimizing the local electronic structure and spatial confinement structure design of rare-earth-based catalysts but also provide valuable insights for designing other types of catalysts.