苝
三联苯
材料科学
三元运算
二面角
堆积
密度泛函理论
分子间力
溶解度
光化学
结晶学
分子
有机化学
计算化学
化学
氢键
程序设计语言
计算机科学
作者
Soo-Yeon Kim,Chihyung Lee,Sunhee Lee,Seung Hun Baek,Doo‐Hyun Ko,Won‐Sik Han
标识
DOI:10.1016/j.jmrt.2022.02.026
摘要
In this study, ortho-terphenyl groups were introduced at the 1- and 7-bay positions of PDI (PDI–TP), and their effect on the photophysical and electrochemical properties were studied along with density functional theory calculations. The PDI core in PDI–TP became highly twisted and exhibited a dihedral angle 12°; while, the unsubstituted PDI compound maintained a planar structure. Furthermore, PDI–TP exhibited a distorted geometry, which reduced the intermolecular π-π stacking between the PDI core and terphenyl group, as evidenced by its increased solubility in common organic solvents. Finally, ternary OSCs were fabricated using PDI–TP as a third component and evaluated in an indoor lighting environment. The ternary OSCs exhibited a power conversion efficiency of up to 20.02%, which is improved by about 28% in comparison to binary OSCs under same condition. This indicates that PDI−TP play an important role as third components in ternary OSCs.
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