Inorganic ligand-supported Mo oxide as a hydrogen atom transfer photocatalyst for direct C(sp2)–H phosphorylation

Visible-light-induced C(sp 2 )–H phosphorylation of 2 H -thiozoles/quinoxalines with H-phosphine oxides was achieved using an inorganic ligand-supported Mo oxide ([N(C 4 H 9 ) 4 ] 2 [Mo 6 O 19 ]) as a hydrogen atom transfer (HAT) photocatalyst.