The significance of fluorinated compound chain length, treatment technology, and influent composition on per‐ and polyfluoroalkyl substances removal in worldwide wastewater treatment plants

Wastewater treatment plants (WWTPs) are deemed major conveyors and point sources of per- and polyfluoroalkyl substances (PFAS) to the environment. This statistical meta-analysis of existing literature from the past 15 years focused on the significance of treatment type for PFAS removal efficiencies and the influence of PFAS sources (domestic vs. industrial) on their removal. Different sampling events, WWTPs across the world, different treatment technologies, configurations, and processes, as well as different PFAS classes and compounds were considered. This study evaluated 13 PFAS analyzed predominantly in 161 WWTPs across the world. The statistical test results revealed that these 13 frequently detected and reported PFAS can be divided into four groups based on their behavior during wastewater treatment, namely (1) C6-10 perfluorocarboxylic acids (PFCAs), (2) C4,5,11,12 PFCAs, (3) C4,6,8 perfluoroalkane sulfonic acids (PFSAs), and (4) C10 PFSA. In this study, biological treatments such as (1) membrane bioreactors, (2) combination of two or more biological treatments, and (3) biofilm processes revealed the highest PFAS removals, although the addition of a tertiary treatment actually had a nonbeneficial effect on PFAS removal. Moreover, a strong statistical correlation was observed between industrial wastewater sources and the presence of high influent PFAS concentrations in the receiving WWTPs. This indicates that industrial sources were the main contributors of the PFAS load in the analyzed WWTPs. Integr Environ Assess Manag 2024;20:59-69. © 2023 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals LLC on behalf of Society of Environmental Toxicology & Chemistry (SETAC).