化学
催化作用
离子液体
硝基
纳米颗粒
纤维素
还原剂
抗坏血酸
胶体金
醛
多相催化
酰胺
绿色化学
扫描电子显微镜
核化学
有机化学
无机化学
化学工程
材料科学
复合材料
工程类
烷基
食品科学
作者
Anoop Singh,Narinder Singh,Navneet Kaur,Doo Ok Jang
摘要
In response to the increasing need for green and cost‐effective catalysts, a novel biomass‐derived heterogeneous catalyst that is effective in a number of environmentally friendly applications has been synthesized. The heterogeneous catalyst ( Au@CIL ), composed of ionic‐liquid‐functionalized cellulose embedded with Au nanoparticles (NPs), was developed for the selective reduction of the nitro group. The Au NPs are formed by the reduction of Au 3+ to Au 0 with ascorbic acid while embedded in the solid support system. The presence of embedded Au NPs was confirmed using infrared spectroscopy, powder X‐ray diffraction, scanning electron microscopy, zeta‐potential measurements, energy‐dispersive X‐ray analysis, elemental dot mapping, and atomic force microscopy. In water at 30 °C, the heterogeneous catalyst Au@CIL selectively transforms aromatic nitro compounds into the corresponding amines in the presence of other functional groups, such as hydroxy, amino, aldehyde, carboxylic acid, and amide.
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