材料科学
阴极
电化学
氧化物
插层(化学)
离子
铜
相变
化学工程
钠
电极
无机化学
热力学
冶金
物理化学
化学
工程类
有机化学
物理
作者
Honghao Deng,Liying Liu,Zhicong Shi
标识
DOI:10.1016/j.matlet.2023.134113
摘要
Layered oxide cathode materials in batteries usually experience complex phase transition during intercalating-deintercalating reaction, leading to poor cycle stability. However, high entropy oxides (HEOs) which can suppress the intermediate phase change have been reported with stable crystal structure and improved cycle stability as cathode materials for sodium-ion batteries (SIBs). Here we synthesize a non-toxic Cu substituted HEOs NaNi0.4-xCuxFe0.2Mn0.2Ti0.2O2 (x = 0, 0.1, 0.2, 0.3, 0.4) via high temperature solid-state reaction, and the effect of Cu substitution is analyzed in detail. NaNi0.3Cu0.1Fe0.2Mn0.2Ti0.2O2 delivers an initial specific capacity of 123.6 mA h g−1 at 0.1C rate corresponding to a capacity retention of 90.05 % after 50 cycles, while NaNi0.4Fe0.2Mn0.2Ti0.2O2 delivers a reversible an initial specific capacity of 129.1 mA h g-1corresponding to a capacity retention of 74.83 %. Cu substitution inhibits the phase transition and improve cycle stability of the material during cycling without sacrificing much capacity. This result constitutes a step forward in increasing the practicality of SIBs.
科研通智能强力驱动
Strongly Powered by AbleSci AI