化学
荧光团
荧光
芘
联氨(抗抑郁剂)
分子内力
组合化学
亲核细胞
亲核加成
光化学
有机化学
色谱法
催化作用
量子力学
物理
作者
Qinglin Mo,Shuai Peng,Wenbin He,Shuyan Ye,Zhenzhong Gao,Xianfeng Hou
出处
期刊:Tetrahedron
[Elsevier BV]
日期:2024-05-09
卷期号:161: 134006-134006
被引量:1
标识
DOI:10.1016/j.tet.2024.134006
摘要
This paper presents a novel fluorescent probe (GNEM) based on a pyrene fluorophore, with dicarboximide as the recognition unit for hydrazine. The fluorescence probe can be synthesized in a simple one-step process. A highly selective and sensitive fluorescence turn-on GNEM synthesized. GNEM react with hydrazine through nucleophilic addition, leading to the deprotection of dicarboximide and the release of dicarboximide hydrazine, resulting in significant blue fluorescence. This enhanced emission is attributed to the intramolecular charge transfer (ICT) sensing mechanism of GNEM. In addition, detection of hydrazine in soil and water is conducted. By designing a simple detection device, the hydrazine content in the air can be quantitatively measured.
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